CSCA Academy / Chemistry / Basic concepts and calculations
CSCA Chemistry · Lesson 4 of 21Gases and the ideal gas equation
Gaz et équation des gaz parfaits · الغازات ومعادلة الغاز المثالي
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Equal volumes of gases at the same temperature and pressure contain the same number of molecules. That makes gas volumes easy to calculate.
Key ideas
- Avogadro: equal volumes of gases (same T and p) contain equal numbers of moles.
- At STP (0 °C, 101 kPa), 1 mol of any gas occupies 22.4 L.
- Ideal gas equation: pV = nRT (p in Pa, V in m³, T in K).
- Gas density ρ = pM/(RT): heavier gases are denser.
Formulas to know
- V = n × 22.4 L (at STP)
- pV = nRT, R = 8.314 J/(mol·K)
- M = 22.4 × ρ (STP, ρ in g/L)
Worked example
Volume of 8.8 g of CO₂ (M = 44 g/mol) at STP?
- Moles: n = 8.8 / 44 = 0.2 mol
- STP: 1 mol occupies 22.4 L
- Multiply: V = 0.2 × 22.4 = 4.48 L
Answer: 4.48 L
Practice questions
1. Moles in 11.2 L of O₂ at STP?
0.5 mol ✓ · 2 mol · 1 mol · 0.25 mol
11.2 / 22.4 = 0.5.
2. 1 L each of H₂, O₂ and CO₂ at the same T and p. Which has the most molecules?
H₂ · O₂ · CO₂ · All equal ✓
Avogadro's law.
3. A gas has density 1.25 g/L at STP. Molar mass?
28 g/mol ✓ · 14 g/mol · 32 g/mol · 44 g/mol
1.25 × 22.4 = 28.